A common heterocyclic compound, 13750-62-4, name is 1-Benzyl-2-methyl-1H-imidazole, molecular formula is C11H12N2, its traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route. 13750-62-4.
The 1-benzyl-2-methylimidazole (0.64 cm3, ?4 mmol) was added to the solution of NiCl2¡¤6H2O (0.24 g, ?1 mmol) and NH4SCN (0.15 g, 2 mmol) in methanol (50 cm3). The mixture was refluxed for about 2 h and after the time the reaction solution was filtered and blue single crystals were obtained by slow evaporation of the solvent.(0013)(3): IR (KBr): 3119, 3030 nuArH; 2954 nuCH; 2094 nu(CN from SCN); 1537 nuCN, 1495 nuC=C; 1451, 1415 1351 delta(C-CH in the plane); 1280, 1140 delta(N-CH in the plane); 988 delta(CH3); 726 nu(SC from SCN).(0014)UV-Vis (methanol, lambda (nm): 1069.7, 647.8, 414.5, 267.6, 264.3, 258.2, 252.2, 247.2, 211.4.
The synthetic route of 1-Benzyl-2-methyl-1H-imidazole has been constantly updated, and we look forward to future research findings.
Reference:
Article; Ma?ecki; Maro?; Polyhedron; vol. 50; 1; (2013); p. 452 – 460;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem