Sloboda-Rozner, Dorit published the artcileA Water-Soluble and “Self-Assembled” Polyoxometalate as a Recyclable Catalyst for Oxidation of Alcohols in Water with Hydrogen Peroxide, COA of Formula: C8H13ClN2O, the publication is Journal of the American Chemical Society (2003), 125(18), 5280-5281, database is CAplus and MEDLINE.
A water-soluble polyoxometalate, Na12[WZnZn2(H2O)2(ZnW9O34)2], synthesized from readily available zinc nitrate and sodium tungstate in the presence of nitric acid, is an effective catalyst for the preparation of ketones and carboxylic acids by selective alc. oxidation with hydrogen peroxide in biphasic (water-alc.) reaction media. Carboxylic acids are obtained by oxidation of primary alcs. with hydrogen peroxide in the presence of Na12[WZnZn2(H2O)2(ZnW9O34)2]; addition of catalytic amounts of TEMPO to oxidation mixtures yields increased proportions of the aldehyde in addition to the carboxylic acid. Secondary alcs. are oxidized in preference to primary alcs. to give ketones; carbon-carbon bond cleavage byproducts are seen in one case. The catalyst generated in situ is as active as the isolated catalyst; in addition, the catalyst can be separated and recycled without losses in either selectivity or in activity.
Journal of the American Chemical Society published new progress about 79047-41-9. 79047-41-9 belongs to imidazoles-derivatives, auxiliary class Imidazole,Chloride,Alcohol, name is (2-Butyl-4-chloro-1H-imidazol-5-yl)methanol, and the molecular formula is C12H25Br, COA of Formula: C8H13ClN2O.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem