X-ray diffraction studies of electrochemical graphite intercalation compounds of ionic liquids was written by Sutto, Thomas E.;Duncan, Teresa T.;Wong, Tiffany C.. And the article was included in Electrochimica Acta in 2009.Reference of 157310-73-1 The following contents are mentioned in the article:
Electrochem. intercalation studies are used to characterize ionic liquids composed of a variety of cationic and anionic species. Electrochem., the ionic liquids are characterized by cyclic voltammograms and charge-discharge experiments for the intercalation and de-intercalation of the various cationic and anionic species into graphite. X-ray structure anal. is also performed to determine the relation between the electrochem. behavior of the ionic liquids, and the formation of intercalated graphitic compounds Two different types of imidazolium cations are studied, specifically the di- and trisubstituted imidazolium. These cations are paired with the following anions: tetrafluoroborate, hexafluorophosphate, bis(trifluoromethanesulfonyl)imide, bis(perfluoroethanesulfonyl)imide, nitrate and H sulfate. Results indicate stronger intercalation chem. for the trisubstituted imidazoliums, correlating with the greater charge-discharge efficiencies found for these types of ionic liquids Many of the anions exhibit very poor charge-discharge efficiencies, correlating to very poorly formed graphite intercalates. The exception to this is the H sulfate intercalate, which had low charge-discharge efficiencies but formed a well defined graphite intercalate. Only the imide based anions exhibited both high charge-discharge efficiencies and the formation of a clearly defined graphite intercalate. This study involved multiple reactions and reactants, such as 1,2-Dimethyl-3-propyl-1H-imidazol-3-ium hexafluorophosphate(V) (cas: 157310-73-1Reference of 157310-73-1).
1,2-Dimethyl-3-propyl-1H-imidazol-3-ium hexafluorophosphate(V) (cas: 157310-73-1) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3鈥揅6) is higher than in water and generally decreases with a Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Reference of 157310-73-1
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem