Two novel Co (II) bifunctional MOFs: Syntheses and applications in photocatalytic degradation of dyes and electrocatalytic water oxidation was written by Cui, Guanning;Liu, Wenbo;Wang, Lulu;Wu, Ruixue;Bi, Caifeng;Zhang, Dongmei;Fan, Yuhua. And the article was included in Journal of Solid State Chemistry in 2021.Safety of 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:
Two novel Co (II) MOFs based on 5-(4-(imidazolyl-1-yl)phenyl) isophthalic acid (H2L), [Co(L)(tib)(H2O)2]n (CP 1) and [Co(L)(bip)0.5]n (CP 2) (tib = 1,3,5-tris (1-imidazolyl) benzene, bip = 3,5-bis(1-imidazolyl) pyridine ether) were synthesized under solvothermal conditions and characterized by powder x-ray diffraction, single crystal x-ray diffraction. The photodegradation studies demonstrate that CPs 1–2 show high-efficiency degradation of MV (Methyl violet), and the mechanism studies demonstrate that the main active species are ·OH radicals. Meanwhile, electrochem. studies demonstrate that CPs 1–2 can catalyze water oxidation under alk. conditions, and CPs 1–2 only need the overpotential of 348 mV-760 mV to deliver the c.d. of 1 mA cm-2. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Safety of 3,5-Di(1H-imidazol-1-yl)pyridine).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is a heterocyclic compound with a five-membered planar ring. It is amphoteric and highly polar. Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Safety of 3,5-Di(1H-imidazol-1-yl)pyridine
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem