Tuning Proton Exchange and Transport in Protic Ionic Liquid Solution through Anion Chemistry was written by Huang, Gongyue;Porcarelli, Luca;Forsyth, Maria;Zhu, Haijin. And the article was included in Journal of Physical Chemistry Letters in 2021.SDS of cas: 478935-29-4 The following contents are mentioned in the article:
Herein, we demonstrate that the p.d. of proton reduction and hydrogen gas oxidation of protic ionic liquids is closely related to the proton exchange rate in the electrolyte. Through a careful design of anion chem., the proton exchange rate can be boosted by several orders of magnitude, reaching 200 kHz at 100°C. It is found that the enhanced proton exchange rate can effectively decrease the potential loss at the electrode, most likely through alleviating the H+ concentration gradient incurred by electrochem. reactions at the electrode surfaces. This research therefore highlights the strategy of using anions of medium-strength acids, such as H2PO4–, for protic ionic liquids with enhanced proton exchange capability. This study involved multiple reactions and reactants, such as 1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate (cas: 478935-29-4SDS of cas: 478935-29-4).
1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate (cas: 478935-29-4) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.SDS of cas: 478935-29-4
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem