Clean synthesis of adipic acid by catalytic oxidation of cyclohexene in acidic ionic liquid was written by Wang, Xiaodan;Cui, Tianfang;Yu, Xiulan. And the article was included in Shenyang Huagong Daxue Xuebao in 2012.Related Products of 478935-29-4 The following contents are mentioned in the article:
Without any organic solvent and halide, oxidation of cyclohexene to adipic acid with aqueous 30% hydrogen peroxide catalyzed by tungstic acid/acidic ionic liquids was carried out. When the molar ratio of cyclohexene, tungstic acid, N-methylimidazolium hydrosulfate ([HMM]HSO4) and hydrogen peroxide was 50:1:5:220 ([HMM]HSO4, 10 mmol), the isolated yield of adipic acid could reach 90.5% for 7.5 h under reflux temperature Such yield was the same or better than that obtained from the present research. The catalyst was cheap, easily prepared and environment friendly, and it could be recycled easily with no loss of the activity. This study involved multiple reactions and reactants, such as 1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate (cas: 478935-29-4Related Products of 478935-29-4).
1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate (cas: 478935-29-4) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Related Products of 478935-29-4
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem