Indirect electrochemistry oxidation of alcohol to aldehyde in ionic liquid was written by Zhao, Xin-hua;Jiang, Xiao-min;Xie, Jiao. And the article was included in Guangzhou Huagong in 2013.Name: 1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate The following contents are mentioned in the article:
The indirect electrochem. oxidation of alc. could be carried out in the protonic ionic liquid methylimidazolium hydrogen sulfate with high selectivity-and current efficiency. The reaction consumed alc. and produced the corresponding aldehyde with the co-product of hydrogen gas in the electrochem. oxidation of alc. Further more, the corresponding carbonyl products could be separated from the electrolyte solution by the refluxing method, and the electrolyte solution could be recycled without apparent decrease in activity. Thus, this approach avoided the problematic by products and separation difficulty in the preparation of the short chain aliphatic aldehydes. This study involved multiple reactions and reactants, such as 1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate (cas: 478935-29-4Name: 1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate).
1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate (cas: 478935-29-4) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Name: 1-Hexyl-3-methyl-1H-imidazol-3-ium hydrogensulfate
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem