Lee, Shao-Chi published the artcileNickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction, Synthetic Route of 258278-25-0, the publication is Chemical Communications (Cambridge, United Kingdom) (2019), 55(99), 14984-14987, database is CAplus and MEDLINE.
The first nickel-catalyzed intramol. hydroacylation/Suzuki cross coupling cascade of phenylboronic acid neopentyl glycol esters I (R = Ph, anthracen-9-yl, thiophen-2-yl, etc.) with a broad range of o-allylbenzaldehydes 2-CH2=CHCH2-4-R3-5-R2-6-R1C6HCHO (R1 = H, R2 = H, OMe; R1R2 = CH=CHCH=CH; R3 = H, OMe, Me, F) has been developed. This strategy shows high regioselectivity and step economy in the construction of two C-C bonds via aldehyde C-H bond activation, affording valuable indanones II with high efficiency.
Chemical Communications (Cambridge, United Kingdom) published new progress about 258278-25-0. 258278-25-0 belongs to imidazoles-derivatives, auxiliary class Achiral NHCs Ligands, name is 1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazol-3-ium chloride, and the molecular formula is C27H39ClN2, Synthetic Route of 258278-25-0.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem