Castillo, Ivan published the artcileSynthesis, spectroscopic, and structural characterization of mixed thioether-benzimidazole copper complexes, Computed Properties of 4760-35-4, the publication is Polyhedron (2015), 824-829, database is CAplus.
Mixed N,S tripodal ligands bis(2,4-dimethylphenylthioethyl)(2-methylbenzimidazolyl)amine L1, bis(2,4-dimethylphenylthioethyl)(1-methyl-2-methylbenzimidazolyl)amine L2, and bis(1-methyl-2-methylbenzimidazolyl)(2-methylthioethyl)amine L3 were employed to prepare the corresponding copper complexes. L1 and L2 associate weakly with Cu2+, while the reaction of CuI with L1 affords [L1CuI]. This was characterized in the solid state by the chelating tridentate coordination mode of L1, with a free thioether, and a terminal iodide, in contrast with the commonly observed Cu-I-Cu bridges. For L3, Cu+ and Cu2+ complexes are accessible as [L3Cu]PF6, and the crystallog. characterized [L3CuCl]Cl. The latter has a square pyramidal coordination around the Cu2+ ion, with the thioether as an axial ligand that remains coordinated in solution, as evidenced by UV-visible spectroscopy.
Polyhedron published new progress about 4760-35-4. 4760-35-4 belongs to imidazoles-derivatives, auxiliary class Chloride,Benzimidazole, name is 2-(Chloromethyl)-1-methyl-1H-benzo[d]imidazole, and the molecular formula is C9H9ClN2, Computed Properties of 4760-35-4.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem