Popov, I. I. published the artcile(1-Methylbenzimidazo-2-yl)carbene. Reaction of 1-methyl-2-(chloromethyl)benzimidazole with nucleophiles, Computed Properties of 4760-35-4, the publication is Khimiya Geterotsiklicheskikh Soedinenii (1989), 1422, database is CAplus.
Treating 2-(chloromethyl)-1-methylbenzimidazole (I) with aqueous NH3 in the presence of 40% aqueous NaOH gave 2-(aminomethyl)-1-methylbenzimidazole. Under phase-transfer catalyzed conditions (50% NaOH, Et3(PhCH2)N+Cl–) in Me2CO or DMSO pyrazinobisbenzimidazole II was formed, but in DMF or EtOH 2-(dimethylamino)- and 2-ethoxy-1-methylbenzimidazoles were obtained, resp.
Khimiya Geterotsiklicheskikh Soedinenii published new progress about 4760-35-4. 4760-35-4 belongs to imidazoles-derivatives, auxiliary class Chloride,Benzimidazole, name is 2-(Chloromethyl)-1-methyl-1H-benzo[d]imidazole, and the molecular formula is C9H9ClN2, Computed Properties of 4760-35-4.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem