Significant effect of 5,10,15,20-meso-tetraarylporphyrinatoiron(III) chloride/triflate and acidic/neutral/basic imidazolium ionic liquids in catalytic oxidation of phenols was written by Ahmad, Sohail;Gautam, Renu;Singhal, Anchal;Chauhan, S. M. S.. And the article was included in Journal of Molecular Liquids in 2018.Category: imidazoles-derivatives This article mentions the following:
The influence of acidic, neutral and basic ionic liquids and their binary mixture with dichloromethane on the reactivity of iron(III) porphyrins was investigated during oxidation of phenols with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chloride and 5,10,15,20-tetraarylporphyrinatoiron(III) triflate. The generation of different intermediates of iron(III) porphyrin in different ILs was studied through viscosity, d., UV-Vis and 1H NMR spectroscopy. The heterolytic cleavage efficiency of (TAP)FeIII-OOH and formation of quinone using iron(III)porphyrin (TAP)FeIIICl with Cl atom as an axial ligand, is influenced by the structure of imidazolium moiety and the counter-anion following the order [(CH2)4SO3HMIm]CF3COO > [Hmim]CF3COO > [bmim]TFA >>>> negligible amount in [bmim]CF3SO3, [Hmim]CF3SO3, [bmim]BF4, [bmim]PF6 and [bmim]Cl. On the other hand, the heterolytic cleavage efficiency of (TAP)FeIII-OOH with iron(III)porphyrin (TAP)FeIIICF3SO3 with triflate as an axial ligand, was found in the following order [(CH2)4SO3HMIm]CF3SO3 > [Hmim]CF3SO3 > [(CH2)4SO3HMIm]CF3COO > [Hmim]CF3COO > [bmim] CF3COO > [bmim]PF6 â?[bmim]BF4 â?[bmim]CF3SO3, while epoxidation and polymerization were mainly observed in basic and neutral ILs. The reactive intermediates formed by the reaction of monooxygen donors with (TAP)FeIIICl varied with ILs, as (TAP)+·FeIV = O intermediate was dominated in acidic ILs, while (TAP)FeIV = O was formed in neutral ILs and (TAP)FeIII-OO– was formed in basic ILs. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Category: imidazoles-derivatives).
1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Category: imidazoles-derivatives
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem