Paramagnetic ionic liquid-coated SiO2@Fe3O4 nanoparticles-The next generation of magnetically recoverable nanocatalysts applied in the glycolysis of PET was written by Cano, Israel;Martin, Carmen;Fernandes, Jesum Alves;Lodge, Rhys W.;Dupont, Jairton;Casado-Carmona, Francisco A.;Lucena, Rafael;Cardenas, Soledad;Sans, Victor;de Pedro, Imanol. And the article was included in Applied Catalysis, B: Environmental in 2020.Formula: C4H7ClN2 This article mentions the following:
The functionalization of silica-coated, magnetic Fe3O4 nanoparticles, with an iron-containing ionic liquid, allows for the synthesis of a Fe3O4@SiO2@(mim)[FeCl4] system that can be employed as a magnetically recoverable nanocatalyst. Herein, we present the use of Fe3O4@SiO2@(mim)[FeCl4] for the glycolysis of PET into BHET under conventional heating. The catalyst achieved nearly 100% yield and selectivity over twelve consecutive reaction cycles at 180 °C and was efficiently recovered without tedious work-up or purification processes. Addnl. analyses revealed that the amount of catalyst lost after each cycle was negligible and no trace of Fe was found in the purified BHET product. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Formula: C4H7ClN2).
1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Formula: C4H7ClN2
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem