Novel Mn(II)-Based Metal-Organic Frameworks Isolated in Ionic Liquids was written by Xu, Ling;Kwon, Young-Uk;de Castro, Baltazar;Cunha-Silva, Luis. And the article was included in Crystal Growth & Design in 2013.HPLC of Formula: 79917-89-8 This article mentions the following:
An unprecedented series of Mn2+-based metal-organic framework (MOF) materials prepared and isolated in ionic liquids (ILs) is reported. Ionothermal reactions of Mn(OAc)2 with H3btc (benzene-1,3,5-tricarboxylic acid) in two groups of [rmi]X (rmi = 1-alkyl-3-methylimidazolium; r = Et or Pr, X = Cl, Br, or I) ILs produced three slightly different 3D MOFs formulated as [rmi][Mn(btc)] [r = Et (1), Pr (2), and (3)], whose architectures can be envisaged as (3,6)-connected pyr topol. nets. Compounds 1–3 are the preferred products when the metal center is half filled d-shelled Mn with the cations of ILs being [emi]+ or [pmi]+. The comparison of the ionothermal synthesized M-btc systems suggests a significant combinatorial influence of metal-direction and ILs’ cationic template, contrasting with subtle effect of ILs’ halides on the MOF structures. In the experiment, the researchers used many compounds, for example, 1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8HPLC of Formula: 79917-89-8).
1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).HPLC of Formula: 79917-89-8
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem