Shi, Xing-Xing published the artcileMonitoring fragmentation and oligomerization of a di-μ-methoxo bridged copper(II) complex: structure, mass spectrometry, magnetism and DFT studies, Application In Synthesis of 7467-35-8, the publication is Dalton Transactions (2019), 48(34), 13094-13100, database is CAplus and MEDLINE.
Analyses of the structural information of mol. fragments from the mass spectra of the solid-state products and their reaction solutions allow for the understanding of their formation and of their diverse properties. The reaction of CuCl2 and (1-methyl-1H-benzo[d]imidazole-2-yl)methanol (HL) led only to crystals containing mol. dimers of [Cu2(L)2Cl2] (Cu2). The CuII-CuII distance and Cu-OR-Cu angle in the structure are 3.044 Å and 104.8°, resp. The magnetic susceptibility (3-400 K) was characterized by a very strong intradimer antiferromagnetic interaction of J = -465 and interdimer zj = -0.83 cm-1. But mass spectrometry of a dissolved single crystal in different source energies identifies both its fragmentation and oligomerization to [CuII3] and [CuII4]. DFT calculations give the relative stabilization energies of the fragments observed in ESI-MS to provide a formation process.
Dalton Transactions published new progress about 7467-35-8. 7467-35-8 belongs to imidazoles-derivatives, auxiliary class Benzimidazole,Alcohol, name is (1-Methyl-1H-benzo[d]imidazol-2-yl)methanol, and the molecular formula is C8H6F3NO, Application In Synthesis of 7467-35-8.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem