Category: 5036-48-6

He, Liting; Xiong, Kai; Wang, Lili; Guan, Ruilin; Chen, Yu; Ji, Liangnian; Chao, Hui published an article in 2021, the title of the article was Iridium(III) complexes as mitochondrial topoisomerase inhibitors against cisplatin-resistant cancer cells.Formula: C6H11N3 And the article contains the following content:

Herein, we developed the first metal-based mitochondrial topoisomerase inhibitors to achieve an effective therapeutic outcome for the therapy of cisplatin-resistant tumor cells. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Formula: C6H11N3

The Article related to iridium complex mitochondrial topoisomerase inhibitor cisplatin resistant tumor cell, Pharmacology: Effects Of Neoplasm Inhibitors and Cytotoxic Agents and other aspects.Formula: C6H11N3

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Muljana, Henky; Remerie, Klaas; Boven, Gert; Picchioni, Francesco; Bose, Ranjita K. published an article in 2022, the title of the article was Crosslinking of Polypropylene with Thiophene and Imidazole.Safety of N-(3-Aminopropyl)-imidazole And the article contains the following content:

In this work, two novel routes to synthesis crosslinked polypropylene (PP) are introduced by using two different precursors (2-thiophenemethyl amine (TMA) and 1-(3 aminopropyl) imidazole (API)), both crosslinked with 1,1′-(methylenedi-4,1-phenylene) bismaleimide (BM) at two different annealing temperature values (T = 50°C and T = 150°C). Both Diels-Alder (DA) and Michael addition reactions were successfully performed with TMA and API, resp., albeit with different reactivity. Imidazole clearly shows a higher reactivity compared to thiophene. In addition, an increase in annealing temperature leads to a higher degree of crosslinking. The highest degree of crosslinking was obtained by the imidazole product after annealing at 150°C (IMG1A150) as evident from the highest complex viscosity (η*) value of IMG1A150. A difference in rheol. and thermal properties between the imidazole and thiophene crosslinked products was also observed However, both products have superior melt properties and thermal stability compared with the starting material. They show processability at high temperatures The melt flow behavior and de-crosslinking at higher temperatures can be tuned depending on the choice of imidazole or thiophene. This study shows an advance on the crosslinked PP processing and its product performances for further application on the com. scale. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Safety of N-(3-Aminopropyl)-imidazole

The Article related to polypropylene thiophene imidazole crosslinking, diels–alder, cross-linked, imidazole-bismaleimide, polypropylene, thermo-reversible, thiophene-bismaleimide, Chemistry of Synthetic High Polymers: Chemical Transformation Of Polymers and other aspects.Safety of N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On May 14, 2021, Yang, Rui; Dai, Pei; Zhang, Shu; Xu, Ri-Wei; Hong, Song; Lin, Wen-Feng; Wu, Yi-Xian published an article.Product Details of 5036-48-6 The title of the article was In-situ synthesis of cross-linked imidazolium functionalized Poly(styrene-b-isobutylene-b-styrene) for anion exchange membranes. And the article contained the following:

The crosslinked imidazolium functionalized anion-exchange membranes is in-situ prepared via reaction of chloromethylated poly(styrene-b-isobutylene-b-styrene) with 1,1′-(1,6-hexanediyl)bisimidazole and N-methylimidazole. The composite membranes of cross-linked imidazolium poly(styrene-b-isobutylene-b-styrene) with a small amount of modified graphene oxide grafted with octadecyl and Pr Ph imidazolium could be further prepared These membranes exhibit significantly high chem. stability and ionic conductivity (σ), marked by low methanol permeability, together with improved dynamic mech. properties. The ionic conductivity of crosslinked imidazolium poly(styrene-b-isobutylene-b-styrene) reaches 2.09 x 10-2 S cm-1 at 80°C by introduction of 0.5 wt% loading of modified graphene oxide. This membrane also behaves an excellent chem. stability and σ can remain ca. 82% of the original value after immerged in strong alk. medium (2 M NaOH) at 60°C for 500 h, which is almost the same as that (ca. 82%) of com. Nafion 115 in acid medium (2 M H2SO4) at 60°C for 500 h. The cross-linked imidazolium poly(styrene-b-isobutylene-b-styrene) is characterized as a promising anion exchange membrane materials in fuel cell for its high ionic conductivity, chem. stability and low methanol permeability. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Product Details of 5036-48-6

The Article related to crosslinked imidazolium functionalized polystyrene isobutylene triblock copolymer, anion exchange membrane, Chemistry of Synthetic High Polymers: Chemical Transformation Of Polymers and other aspects.Product Details of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On April 19, 2022, Santa Chalarca, Cristiam F.; Dalal, Rishad J.; Chapa, Alejandra; Hanson, Mckenna G.; Reineke, Therefsa M. published an article.Electric Literature of 5036-48-6 The title of the article was Cation Bulk and pKa Modulate Diblock Polymer Micelle Binding to pDNA. And the article contained the following:

Polymer-based gene delivery relies on the binding, protection, and final release of nucleic acid cargo using polycations. Engineering polymeric vectors, by exploring novel topologies and cationic moieties, is a promising avenue to improve their performance, which hinges on the development of simple synthetic methods that allow facile preparation In this work, we focus on cationic micelles formed from block polymers, which are examined as promising gene compaction agents and carriers. In this study, we report the synthesis and assembly of six amphiphilic poly(Bu acrylate)-b-poly(cationic acrylamide) diblock polymers with different types of cationic groups ((dialkyl)amine, morpholine, or imidazole) in their hydrophilic corona. The polycations were obtained through the parallel postpolymn. modification of a poly(Bu acrylate)-b-poly(pentafluorophenyl acrylate) reactive scaffold, which granted diblock polymers with equivalent ds.p. and subsequent quant. functionalization with cations of different pKa. Ultrasound-assisted direct dissolution of the polycations in different aqueous buffers (pH = 1-7) afforded micellar structures with low size dispersities and hydrodynamic radii below 100 nm. The formation and properties of micelle-DNA complexes (“micelleplexes”) were explored via DLS, zeta potential, and dye-exclusion assays revealing that binding is influenced by the cation type present in the micelle corona where bulkiness and pKa are the drivers of micelleplex formation. Combining parallel synthesis strategies with simple direct dissolution formulation opens opportunities to optimize and expand the range of micelle delivery vehicles available by facile tuning of the composition of the cationic micelle corona. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Electric Literature of 5036-48-6

The Article related to diblock fluoropolymer raft polymerization cationic micelle pdna complex polyplex, Chemistry of Synthetic High Polymers: Chemical Transformation Of Polymers and other aspects.Electric Literature of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On July 5, 2022, Das, Mithun; Baran Bhattacharya, Asit; Rahman Parathodika, Arshad; Naskar, Kinsuk published an article.Synthetic Route of 5036-48-6 The title of the article was Room temperature Self-healable and extremely stretchable elastomer with improved mechanical Properties: Exploring a simplistic Metal-Ligand interaction. And the article contained the following:

The dynamic supramol. crosslinking reactions like imine bond formation, disulfide metathesis reactions, Diels Alder reactions, metal-ligand interactions, H-bonding, and ionic interactions are broadly used for the self-healing application of elastomers. Herein, we have developed a new self-healable and extremely stretchable elastomer based on robustness and dynamic metal-ligand coordination bonds between the API ligand and the Zn2+ metal ion moieties incorporated onto the XNBR rubber backbone. The FT-IR anal. confirmed the formation of amide linkage and metal-ligand coordination bonds into the XNBR rubber backbone. The healing performance and mech. properties of various rubber compounds depend on the dosages of metal ions and the type of crosslinking systems. The metal-ligand crosslink compounds exhibit excellent healing performance over the sulfur crosslinking system. Differential scanning calorimetry, rubber process analyzer, crosslinking d., and morphol. studies are indicated to characterize the metal-ligand interactions in the XNBR rubber matrix. The metal-ligand crosslinked XNBR rubber with 3 parts of Zn2+ metal ion demonstrates an excellent healing performance of 91.2%, with the tensile strength of 5.7±0.8 MPa at room temperature for 24 h is much higher than the covalently crosslinked elastomers. The metal-ligand coordination bonds are entirely dynamic and thermoreversible during the rebuilding process and obtain an excellent self-healing property than the sulfur curing system. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Synthetic Route of 5036-48-6

The Article related to carboxylated nitrile rubber metal ligand interaction self healing, Synthetic Elastomers and Natural Rubber: Physical Properties and Testing and other aspects.Synthetic Route of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Cao, Siyu; Yoshio, Masafumi; Seki, Atsushi published an article in 2020, the title of the article was Ion-conductive nanostructured polymer films formed by photopolymerization of lyotropic columnar liquid-crystalline monomers, composed of a zwitterionic compound and a protic ionic liquid.Related Products of 5036-48-6 And the article contains the following content:

Here, we report on a new family of columnar nanostructured polymer films forming protic nanochannels that exhibit good ionic conductivities in the order of 10-4-10-3 S cm-1 at ambient temperature These polymer films were obtained by the in situ photopolymerization of lyotropic columnar liquid crystals, consisting of a polymerizable taper-shaped zwitterionic compound and a protic ionic liquid (imidazolium bis(trifluoromethylsulfonyl)imide), in the presence of 15 wt% water. The composition of the protic ionic liquid in the mixture was changed from 40 to 60 mol%. The ionic conductivities were measured by an a.c. impedance method. The ionic conductivity increased with the increase of the protic ionic liquid The conductivities of columnar nanostructured polymer films were about 2-3 orders of magnitude higher than those of amorphous polymer films prepared by photopolymerization of the corresponding monomers in an isotropic liquid state. The formation of nanochannels in the polymer matrixes significantly enhanced the ion conduction. The present two-component lyotropic liquid-crystalline self-assembly followed by photopolymerization is a promising approach to the development of high ion-conductive polymer membranes. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Related Products of 5036-48-6

The Article related to lyotropic columnar liquid crystalline monomer photopolymerization ionic conductivity, Physical Properties of Synthetic High Polymers: Physical Properties Of Polymers and other aspects.Related Products of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On September 27, 2022, Le, My Linh; Grzetic, Douglas J.; Delaney, Kris T.; Yang, Kai-Chieh; Xie, Shuyi; Fredrickson, Glenn H.; Chabinyc, Michael L.; Segalman, Rachel A. published an article.Safety of N-(3-Aminopropyl)-imidazole The title of the article was Electrostatic Interactions Control the Nanostructure of Conjugated Polyelectrolyte-Polymeric Ionic Liquid Blends. And the article contained the following:

Polyelectrolyte complexation offers unique opportunities to compatibilize polymers with different backbone chemistries and to control the morphol. of the resulting blend via electrostatic manipulation. In this study, we demonstrate the ability to formulate homogeneous complexes of a conjugated polyelectrolyte with a polymeric ionic liquid, utilizing the electrostatic attraction among their oppositely charged side chains. Variation of electrostatic parameters, such as counterion concentration or polymer charge fraction, tunes the morphol. of these polymer complexes from homogeneously disordered blend to weakly structured microemulsion where the local ordering arises from backbone-immiscibility-induced microphase segregation. Our exptl. observations are in qual. agreement with both field-theoretic simulation and RPA calculations Simulated morphol. snapshots suggest and exptl. evidence also indicates that the microphase-segregated complex likely takes on a cocontinuous microemulsion structure. Our findings show that ionic interactions are an effective pathway to compatibilize polymers at macroscopic length scales while achieving controlled nanostructures in these ionic blends. Such systems have great potential for engineering the nanostructure of polymers to tailor applications such as nanofiltration, catalysis, and energy storage, where local ordering can enhance the phys. properties of an otherwise macroscopically homogeneous structure. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Safety of N-(3-Aminopropyl)-imidazole

The Article related to electrostatic nanostructure conjugated polyelectrolyte polymeric ionic liquid blend, Physical Properties of Synthetic High Polymers: Physical Properties Of Polymers and other aspects.Safety of N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On May 18, 2022, Ueda, Yuki; Eguchi, Ayano; Tokunaga, Kohei; Kikuchi, Kei; Sugita, Tsuyoshi; Okamura, Hiroyuki; Naganawa, Hirochika published an article.Synthetic Route of 5036-48-6 The title of the article was Urea-Introduced Ionic Liquid for the Effective Extraction of Pt(IV) and Pd(II) Ions. And the article contained the following:

A urea-introduced imidazolium-based ionic liquid (IL), 1-butyl-3-{3-(3-methyl-2H-imidazol-1-yl)propyl}urea bis(trifluoromethylsulfonyl)imide (L1), whose selectivity to Pt(IV) and Pd(II) was changed only by a pH region, was synthesized, and its Pt(IV) and Pd(II) extraction behaviors were investigated. In the conventional organic extraction system, an organic extractant with a urea group, 1-butyl-3-(2-ethylhexyl)urea, in isooctane extracted Pt(IV) and Pd(II) in a similar pH range, the extraction equilibrium half-time (t1/2) of Pd(II) was 8.95 h. In contrast, in the IL extraction system, Pt(IV) and Pd(II) were extracted in the lower and higher pH regions, resp., indicating the mutual separation of Pt(IV) and Pd(II) by pH-change. Furthermore, the extraction equilibrium t1/2 of Pd(II) with the IL extraction system was 0.18 h. UV-visible and extended X-ray absorption fine structure spectroscopies of Pt(IV) and Pd(II) after extraction using the IL were conducted to determine the extraction mechanism. As a result, Pt(IV) was extracted as [PtCl6]2- via anion-exchange (outer-sphere complex). On the other hand, Pd(II) was extracted via a mixed reaction of ligand-exchange (inner-sphere complex) and anion-exchange. Finally, the IL extraction system did not produce a third phase even when loaded with a high concentration of Pt(IV). The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Synthetic Route of 5036-48-6

The Article related to urea introduced ionic liquid extraction platinum palladium ion, Phase Equilibriums, Chemical Equilibriums, and Solutions: Partition, Extraction and other aspects.Synthetic Route of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Liu, Kaixuan; Paulino, Victor; Mukhopadhyay, Arindam; Bernard, Brianna; Kumbhar, Amar; Liu, Chuan; Olivier, Jean-Hubert published an article in 2021, the title of the article was How to reprogram the excitonic properties and solid-state morphologies of π-conjugated supramolecular polymers.Application of 5036-48-6 And the article contains the following content:

The development of supramol. tools to modulate the excitonic properties of non-covalent assemblies paves the way to engineer new classes of semicondcuting materials relevant to flexible electronics. While controlling the assembly pathways of organic chromophores enables the formation of J-like and H-like aggregates, strategies to tailor the excitonic properties of pre-assembled aggregates through post-modification are scarce. In the present contribution, we combine supramol. chem. with redox chem. to modulate the excitonic properties and solid-state morphologies of aggregates built from stacks of water-soluble perylene diimide building blocks. The n-doping of initially formed aggregates in an aqueous medium is shown to produce π-anion stacks for which spectroscopic properties unveil a non-negligible degree of electron-electron interactions. Oxidation of the n-doped intermediates produces metastable aggregates where free exciton bandwidths (ExBW) increase as a function of time. Kinetic data anal. reveals that the dynamic increase of free exciton bandwidth is associated with the formation of superstructures constructed by means of a nucleation-growth mechanism. By designing different redox-assisted assembly pathways, we highlight that the sacrificial electron donor plays a non-innocent role in regulating the structure-function properties of the final superstructures. Furthermore, supramol. architectures formed via a nucleation-growth mechanism evolve into ribbon-like and fiber-like materials in the solid-state, as characterized by SEM and HRTEM. Through a combination of ground-state electronic absorption spectroscopy, electrochem., spectroelectrochem., microscopy, and modeling, we show that redox-assisted assembly provides a means to reprogram the structure-function properties of pre-assembled aggregates. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Application of 5036-48-6

The Article related to conjugated supramol polymer solid state morphol, Physical Properties of Synthetic High Polymers: Physical Properties Of Polymers and other aspects.Application of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On January 27, 2021, Zhang, Huan; Yang, Shijia; Yang, Zhusheng; Wang, Dong; Han, Juanjuan; Li, Cuihua; Zhu, Caizhen; Xu, Jian; Zhao, Ning published an article.Safety of N-(3-Aminopropyl)-imidazole The title of the article was An Extremely Stretchable and Self-Healable Supramolecular Polymer Network. And the article contained the following:

The construction of a single polymer network with extreme stretchability, relatively high mech. strength, and fast and facile autonomous room-temperature self-healing capability still remains a challenge. Herein, supramol. polymer networks are fabricated by synergistically incorporating metal-ligand and hydrogen bonds in poly(propylene glycol) (PPG). The representative specimen, PPG-Im-MDA-1.5-0.25-Cu, shows a combination of notable mech. properties involving an extreme stretching ratio of 346 ± 14x and a Young’s modulus of 2.10 ± 0.14 MPa, which are superior to the previously reported extremely stretchable polymeric materials. Notably, the destroyed specimen can fully recover mech. performances within 1 h. The tunability of mech. properties and self-healing capability has been actualized by merely tailoring the content of a chain extender. The application of the as-prepared supramol. PPG network in constructing a flexible and self-healable conductor has been demonstrated. This strategy provides some insights for preparing extremely stretchable and self-healable polymeric materials. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Safety of N-(3-Aminopropyl)-imidazole

The Article related to stretchable self healable supramol polymer network, ppg, autonomous self-healing, dynamic bond, extreme stretchability, hydrogen bond, metal−ligand bond, Plastics Manufacture and Processing: Formulating Procedures and Compositions and other aspects.Safety of N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem