Category: 5036-48-6

Jiang, Tuo; Bordi, Samuele; McMillan, Angus E.; Chen, Kuang-Yen; Saito, Fumito; Nichols, Paula L.; Wanner, Benedikt M.; Bode, Jeffrey W. published an article in 2021, the title of the article was An integrated console for capsule-based, automated organic synthesis.Application In Synthesis of N-(3-Aminopropyl)-imidazole And the article contains the following content:

Using a combination of reagent design, hardware engineering and a simple operating system, an instrument capable of executing complex organic reactions with prepacked capsules was provided. The machine conducted coupling reactions and delivered the purified products with minimal user involvement. Two desirable reaction classes – the synthesis of saturated N-heterocycles and reductive amination – were implemented, along with multi-step sequences that provided drug-like organic mols. in a fully automated manner. This system would serve as a console for developers to provide synthetic methods as integrated, user-friendly packages for conducting organic synthesis in a safe and convenient fashion. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Application In Synthesis of N-(3-Aminopropyl)-imidazole

The Article related to saturated heterocycle preparation, aldehyde amine capsule based automated organic synthesis, Heterocyclic Compounds (More Than One Hetero Atom): Eight- and Higher-Membered Rings and other aspects.Application In Synthesis of N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On July 31, 2022, Karuk Elmas, Sukriye Nihan; Karagoz, Abdurrahman; Arslan, Fatma Nur; Yilmaz, Ibrahim published an article.Synthetic Route of 5036-48-6 The title of the article was Propylimidazole Functionalized Coumarin Derivative as Dual Responsive Fluorescent Chemoprobe for Picric Acid and Fe3+ Recognition: DFT and Natural Spring Water Applications. And the article contained the following:

A propylimidazole functionalized coumarin derivative (IPC) was fabricated for the first time and applied as a dual responsive fluorescent chemoprobe for sensitive and selective recognition of picric acid (PA) and Fe3+. Strong fluorescence quenching phenomena of the IPC were observed in H2O/ACN (5/95, volume/volume) medium (λem=408 nm) upon the additions of Fe3+ or PA. The fabricated dual responsive IPC offered good selectivity and sensitivity with the low limit of detection values (0.92μM for PA and 0.22μM for Fe3+) lower than the acceptable amounts of Fe3+ and PA by the international official authorities. The validation study for the chemoprobe IPC for PA and Fe3+ was also performed. The interaction phenomena of IPC with PA and Fe3+ based on the findings of a range of experiments were considered and DFT computations were done to verify their recognition mechanisms. The sensing phenomena of IPC towards PA (1:1) and Fe3+ (3:1) were confirmed by the MALDI TOF-MS, FT-IR, 1H-NMR titration and Job’s methods. Furthermore, the compound IPC was effectively applied as a fluorescent sensor for Fe3+ and PA detection in real natural spring water samples. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Synthetic Route of 5036-48-6

The Article related to propylimidazole coumarin preparation picricacid iron natural water fluorescent sensor, coumarin, dft, fluorescent sensor, iron, natural water, picric acid, Optical, Electron, and Mass Spectroscopy and Other Related Properties: Luminescence and other aspects.Synthetic Route of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On February 3, 2021, Du, Liang; Nosratabad, Neda Arabzadeh; Jin, Zhicheng; Zhang, Chengqi; Wang, Sisi; Chen, Banghao; Mattoussi, Hedi published an article.HPLC of Formula: 5036-48-6 The title of the article was Luminescent Quantum Dots Stabilized by N-Heterocyclic Carbene Polymer Ligands. And the article contained the following:

We have tested the ability of N-heterocyclic carbene (NHC)-modified ligands to coordinate and stabilize luminescent CdSe-ZnS core-shell quantum dot (QD) dispersions in hydrophilic media. In particular, we probed the effects of ligand structure and coordination number on the coating affinity to the nanocrystals. We find that such NHC-based ligands rapidly coordinate onto the QDs (requiring ~5-10 min of reaction time), which reflects the soft Lewis base nature of the NHC groups, with its two electrons sharing capacity. Removal of the hydrophobic cap and promotion of carbene-driven coordination on the nanocrystals have been verified by 1H NMR spectroscopy, while 13C NMR was used to identify the formation of carbene-Zn complexes. The newly coated QD dispersions exhibit great long-term colloidal stability over a wide range of conditions. Addnl., we find that coordination onto the QD surfaces affects the optical and spectroscopic properties of the nanocrystals. These include a size-dependent red-shift of the absorption and fluorescence spectra and a pronounced increase in the measured fluorescence intensity when the samples are stored under white light exposure compared to those stored in the dark. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).HPLC of Formula: 5036-48-6

The Article related to luminescent quantum dot stabilized heterocyclic carbene polymer ligand, Optical, Electron, and Mass Spectroscopy and Other Related Properties: Luminescence and other aspects.HPLC of Formula: 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On January 31, 2021, AlNeyadi, Shaikha S.; Adem, Abdu; Amer, Naheed; Ghattas, Mohammad A.; Atatreh, Noor; Salem, Alaa A.; Abdou, Ibrahim M. published an article.COA of Formula: C6H11N3 The title of the article was Activation of the GLP-1 receptor by chloropyrimidine derivatives. And the article contained the following:

The anti-diabetic activities of a series of chloropyrimidine derviativeswere investigated after they were designed, synthesized, and docked against the GLP-1 receptor target. In comparison to exenatide, which was utilized as a reference drug, the three chloropyrimidine synthesized compounds I, II and III exhibited potent in vitro and in vivo antidiabetic activities. Interestingly, compounds I, II and III showed to be the most effective in lowering blood glucose levels and led to even higher glucose uptake than the reference drug, exenatide. Consistent with the in vitro and in vivo data, compounds II and III had the lowest docking energy scores (Glide-XP score = 5.1 kcal/mol) and the greatest ligand efficiency score (> – 0.40 kcal/mol) among all docked compounds These findings give up new possibilities for the development of high-efficacy compounds to treat hyperglycemia. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).COA of Formula: C6H11N3

The Article related to alkylated chloropyrimidine prpen antidiabetic sar mol docking glp receptor, aliphatic and aromatic amine nucleophilic substitution, Heterocyclic Compounds (More Than One Hetero Atom): Pyrimidines and Quinazolines and other aspects.COA of Formula: C6H11N3

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

O’Harra, Kathryn E.; Noll, Danielle M.; Kammakakam, Irshad; DeVriese, Emily M.; Solis, Gala; Jackson, Enrique M.; Bara, Jason E. published an article in 2020, the title of the article was Designing imidazolium poly(amide-amide) and poly(amide-imide) ionenes and their interactions with mono- and tris(imidazolium) ionic liquids.Computed Properties of 5036-48-6 And the article contains the following content:

Here we introduce the synthesis and thermal properties of a series of sophisticated imidazolium ionenes with alternating amide-amide or amide-imide backbone functionality, and investigate the structural effects of mono(imidazolium) and unprecedented tris(imidazolium) ionic liquids (ILs) in these ionenes. The new set of poly(amide-amide) (PAA) and poly(amide-imide) (PAI) ionenes represent the intersection of conventional high-performance polymers with the ionene archetype-presenting polymers with alternating functional and ionic elements precisely sequenced along the backbone. The effects of polymer composition on the thermal properties and morphol. were analyzed. Five distinct polymer backbones were synthesized and combined with a stoichiometric equivalent of the IL 1-benzyl-3-methylimidazolium bistriflimide ([Bnmim][Tf2N]), which were studied to probe the self-assembly, structuring, and contributions of intermol. forces when IL is added. Furthermore, three polyamide (PA) or polyimide (PI) ionenes with simpler xylyl linkages were interfaced with [Bnmim][Tf2N] as well as a novel amide-linked tris(imidazolium) IL, to demonstrate the structural changes imparted by the inclusion of functional, ionic additives dispersed within the ionene matrix. This work highlights the possibilities for utilizing concepts from small mols. which exhibit supramol. self-assembly to guide creative design and manipulate the structuring of ionenes. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Computed Properties of 5036-48-6

The Article related to imidazolium polyamide amide imide ionene ionic liquid, composites, copolymers, ionenes, polyamides, polyelectrolytes, polyimides, Physical Properties of Synthetic High Polymers: Physical Properties Of Polymers and other aspects.Computed Properties of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Waleed, Hadeer Q.; Csecsi, Marcell; Hadjadj, Rachid; Thangaraj, Ravikumar; Pecsmany, Daniel; Owen, Michael; Szori, Milan; Fejes, Zsolt; Viskolcz, Bela; Fiser, Bela published an article in 2022, the title of the article was Computational Study of Catalytic Urethane Formation.Synthetic Route of 5036-48-6 And the article contains the following content:

Polyurethanes (PUs) are widely used in different applications, and thus various synthetic procedures including one or more catalysts are applied to prepare them. For PU foams, the most important catalysts are nitrogen-containing compounds Therefore, in this work, the catalytic effect of eight different nitrogen-containing catalysts on urethane formation will be examined The reactions of Ph isocyanate (PhNCO) and methanol without and in the presence of catalysts have been studied and discussed using the G3MP2BH and HLYP composite method. The solvent effects have also been considered by applying the SMD implicit solvent model. A general urethane formation mechanism has been proposed without and in the presence of the studied catalysts. The proton affinities (PA) were also examined The barrier height of the reaction significantly decreased (螖E0 > 100 kJ/mol) in the presence of the studied catalysts, which proves the important effect they have on urethane formation. The achieved results can be applied in catalyst design and development in the near future. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Synthetic Route of 5036-48-6

The Article related to urethane phenyl isocyanate proton affinity computational study, dft, catalyst-free, catalysts, composite method, proton affinities, urethane formation, Catalysis, Reaction Kinetics, and Inorganic Reaction Mechanisms: Catalytic Reactions and other aspects.Synthetic Route of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On November 30, 2021, Sarikaya, Ikbal; Bilgen, Selcuk; Unver, Yasemin; Inan Bektas, Kadriye; Akbas, Halide published an article.Recommanded Product: 5036-48-6 The title of the article was Preparation, characterization, antibacterial activity, and interfacial and micellar features of cationic gemini surfactants with different spacers. And the article contained the following:

In the present study, four novel imidazolium-based cationic gemini surfactants (IBCGS) have been synthesized, having same hydrocarbon chain lengths and different spacers. The impacts of type and nature of spacer on Krafft temperatures (TK) have been examined Micellization behaviors of IBCGS have been investigated at different temperatures above TK by both surface tension and specific conductivity measurements. Surface activity properties of aqueous systems have been calculated using the results of the measurement data. Critical micelle concentration (CMC), surface pressure at CMC (螤CMC), min. area of head group (Amin), degree of counterion binding (尾), degree of counterion dissociation (伪), and maximum surface excess (螕max) of IBCGS have been calculated with data of surface tension and specific conductivity IBCGS have low CMC values than other imidazole categories of gemini and monomeric cationic surfactants. Micelle aggregation number (Nagg) values have been determined with the steady-state fluorescence quenching method. The values of Nagg have been found in the range of 19-28. Addnl., the antibacterial activities of IBCGS on gram-pos. and gram-neg. bacteria have been investigated. IBCGS studied in this article have showed perfect antibacterial activity particularly against gram-pos. bacteria. The data obtained in this study may be benefical for the surfactant applications in different areas. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Recommanded Product: 5036-48-6

The Article related to cationic gemini surfactant critical micelle concentration antibacterial activity, Surface Active Agents and Detergents: Preparation, Analysis, and Properties Of Surfactants Other Than Soaps and other aspects.Recommanded Product: 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On February 23, 2022, Jones, Seamus D.; Nguyen, Howie; Richardson, Peter M.; Chen, Yan-Qiao; Wyckoff, Kira E.; Hawker, Craig J.; Clement, Raphaele J.; Fredrickson, Glenn H.; Segalman, Rachel A. published an article.SDS of cas: 5036-48-6 The title of the article was Design of Polymeric Zwitterionic Solid Electrolytes with Superionic Lithium Transport. And the article contained the following:

Progress toward durable and energy-dense lithium-ion batteries has been hindered by instabilities at electrolyte-electrode interfaces, leading to poor cycling stability, and by safety concerns associated with energy-dense lithium metal anodes. Solid polymeric electrolytes (SPEs) can help mitigate these issues; however, the SPE conductivity is limited by sluggish polymer segmental dynamics. We overcome this limitation via zwitterionic SPEs that self-assemble into superionically conductive domains, permitting decoupling of ion motion and polymer segmental rearrangement. Although crystalline domains are conventionally detrimental to ion conduction in SPEs, we demonstrate that semicrystalline polymer electrolytes with labile ion-ion interactions and tailored ion sizes exhibit excellent lithium conductivity (1.6 mS/cm) and selectivity (t+ 鈮?0.6-0.8). This new design paradigm for SPEs allows for simultaneous optimization of previously orthogonal properties, including conductivity, Li selectivity, mechanics, and processability. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).SDS of cas: 5036-48-6

The Article related to design polymeric zwitterionic solid electrolytes superionic lithium transport, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.SDS of cas: 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On June 25, 2022, Ahn, Yeonho; Kim, Dukjoon published an article.Quality Control of N-(3-Aminopropyl)-imidazole The title of the article was High energy efficiency and stability of vanadium redox flow battery using pore-filled anion exchange membranes with ultra-low V4+ permeation. And the article contained the following:

Anion exchange membranes for vanadium redox flow battery are prepared by filling pore of polytetrafluoroethylene (PTFE) substrates with poly(arylene ether ketone) with imidazole (PAPI). For facile impregnation of PAPI mols. into pore of hydrophobic PTFE, catechol and polyethyleneimine (PEI) are co-deposited to hydrophilize the surface of PTFE. Compared with the pristine PAPI membranes, dimensional and mech. properties of the pore-filled membranes improved due to the reinforcing effect of PTFE substrate. While this process reduces water uptake and swelling ratio by 10% and 8%, resp., it enhances the tensile strength by 5 folds. Strikingly, the ion conductivity even slightly increases along with the huge reduction of vanadium ion permeability. Pore filed membranes reveal vanadium ion permeability of 1.4 x 10-7 cm2 min-1-2.08 x 10-7 cm2 min-1 at room temperature, which is 10 times and 3 times lower than those of the com. Nafion117 and FAP450 membranes, resp. For the cycling test of VRFB cell with 200 cycles, it shows the coulombic and energy efficiency over 96.5% and 85%, resp., because of the low vanadium permeability. In association with this, the capacity retention behavior is more stable than the com. membranes. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Quality Control of N-(3-Aminopropyl)-imidazole

The Article related to anion exchange membrane vanadium permeation energy redox flow battery, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.Quality Control of N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On October 15, 2021, Liu, Ruihong; Wang, Jin; Che, Xuefu; Wang, Ting; Aili, David; Li, Qingfeng; Yang, Jingshuai published an article.Name: N-(3-Aminopropyl)-imidazole The title of the article was Facile synthesis and properties of poly(ether ketone cardo)s bearing heterocycle groups for high temperature polymer electrolyte membrane fuel cells. And the article contained the following:

Novel high temperature polymer electrolyte membranes (HT-PEMs) are fabricated from com. and low-cost poly (ether ketone cardo) (PEK-Cardo). Rather than normal chloromethylation and quaternization procedure to introduce basic groups into poly (arylene ether)s, three different long side-chain basic groups are grafted into PEK-Cardo through a facile one-step lactamization between the cardo phenolphthalein type moiety in PEK-Cardo and amino compounds (i.e. 1-(3-aminopropyl) imidazole (APIm), 1-(3-aminopropyl) pyrrolidin-2-one (APy) and 3-(dimethylamino)-1-propylamine). The obtained lactamized PEK-Cardo membranes exhibit excellent phosphoric acid doping capability and the physicochem. properties are optimized by adjusting the chem. structure and grafting degree of side-chain basic groups. Fuel cell results demonstrate a big potential for HT-PEM fuel cell applications. Thus, this proposal provides a new, straightforward and low-cost method to prepare high-performance HT-PEMs. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Name: N-(3-Aminopropyl)-imidazole

The Article related to polyether ketone polymer electrolyte membrane fuel cell, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.Name: N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem