Category: imidazoles-derivatives

Takamuku, Toshiyuki et al. published their research in Physical Chemistry Chemical Physics in 2018 | CAS: 404001-48-5

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Category: imidazoles-derivatives

Hydrogen bonds of the imidazolium rings of ionic liquids with DMSO studied by NMR, soft X-ray spectroscopy, and SANS was written by Takamuku, Toshiyuki;Tokuda, Takumi;Uchida, Takahiro;Sonoda, Kazuya;Marekha, Bogdan A.;Idrissi, Abdenacer;Takahashi, Osamu;Horikawa, Yuka;Matsumura, Junya;Tokushima, Takashi;Sakurai, Hiroyuki;Kawano, Masahiro;Sadakane, Koichiro;Iwase, Hiroki. And the article was included in Physical Chemistry Chemical Physics in 2018.Category: imidazoles-derivatives This article mentions the following:

The hydrogen bonds of the imidazolium-ring H atoms of ionic liquids (ILs), 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amides ([Cnmim][TFSA], n = 2 to 12 where n represents the alkyl chain length), with the O atom of DMSO (DMSO) have been elucidated using 1H, 13C, and 15N NMR spectroscopy and soft X-ray absorption and emission spectroscopy (XAS and XES). D. functional theory (DFT) calculations have been performed on an isolated DMSO mol. and two cluster models of [Cnmim]+-DMSO by hydrogen bonding to interpret the XES spectra for the [Cnmim][TFSA]-DMSO solutions The 1H and 13C NMR chem. shifts of the imidazolium ring showed that deshielding of the ring H and C atoms is moderate as the DMSO mole fraction xDMSO increases to ∼0.8; however, it becomes more significant with further increase of xDMSO. This finding suggests that the hydrogen bonds of the three ring H atoms with the DMSO O atoms are saturated in solutions with xDMSO increased to ∼0.8. The 1H and 13C chem. shifts of the alkyl chains revealed that the electron densities of the chain H and C atoms gradually decrease with increasing xDMSO, except for the N1-bound carbon atom C7 of the chain. The 15N NMR chem. shifts showed that the imidazolium-ring N1 atom which is bound to the alkyl chain is shielded with increasing xDMSO in the range from 0 to 0.8 and is then deshielded with further increase of xDMSO. In contrast, the imidazolium ring N3 atom is simply deshielded with increasing xDMSO. Thus, the electron densities of the alkyl chain may be condensed at the C7 and N1 atoms of [Cnmim]+ by the hydrogen bonding of the ring H atoms with DMSO. The hydrogen bonding of DMSO with the ring results in low-energy shifts of the XES peaks of the O K-edge of DMSO. Small-angle neutron scattering experiments showed that [Cnmim][TFSA] and DMSO are homogeneously mixed with each other on the mesoscopic scale. This results from the strong hydrogen bonds of DMSO with the imidazolium-ring H atoms. In the experiment, the researchers used many compounds, for example, 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5Category: imidazoles-derivatives).

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Category: imidazoles-derivatives

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

McCorkill, Mary E. et al. published their research in Industrial & Engineering Chemistry Research in 2019 | CAS: 79917-89-8

1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Quality Control of 1-Methyl-3-propylimidazolium Chloride

Effect of Alkyl Chain Length on Derived Thermodynamic Properties of 1-Alkyl-3-methylimidizolium Chloride Ionic Liquids and Their Mixtures with Ethanol was written by McCorkill, Mary E.;Dickmann, James S.;Kiran, Erdogan. And the article was included in Industrial & Engineering Chemistry Research in 2019.Quality Control of 1-Methyl-3-propylimidazolium Chloride This article mentions the following:

Densities of the ionic liquids [C2C1i.m.]Cl, [C3C1i.m.]Cl, [C4C1i.m.]Cl, and [C6C1i.m.]Cl and their mixtures with EtOH were determined up to 40 MPa and 398 K. D. was modeled as a function of temperature, pressure, and composition using the Sanchez-Lacombe equation of state. Using the model, derived thermodn. properties, isothermal compressibility, isobaric expansivity, and internal pressure, were calculated This allowed for the estimation of the Hildebrand solubility parameters of these ionic liquids (ILs). Internal pressure was found to go through a maximum at low concentrations of ionic liquid in the case of [C3C1i.m.]Cl, [C4C1i.m.]Cl, and [C6C1i.m.]Cl. These observations were interpreted in terms of a significant effect of the alkyl chain length on the interactions between the IL and the cosolvent, EtOH. It is speculated that this is in part due to possible clustering between (Cl–) and EtOH. In the experiment, the researchers used many compounds, for example, 1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8Quality Control of 1-Methyl-3-propylimidazolium Chloride).

1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Quality Control of 1-Methyl-3-propylimidazolium Chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Chen, Liping et al. published their research in Langmuir in 2019 | CAS: 404001-48-5

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Microstructure and Tribological Properties of Lamellar Liquid Crystals Formed by Ionic Liquids as Cosurfactants was written by Chen, Liping;Ge, Lingling;Fan, Lei;Guo, Rong. And the article was included in Langmuir in 2019.Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide This article mentions the following:

Lamellar liquid crystals (LLCs) have been shown to have lubrication properties in many documents due to their bilayer structure. Ionic liquids are often used as additive or surfactant in LLCs. However, ionic liquids used as cosurfactants, which lead to a transition from the hexagonal liquid crystals to LLCs, are relatively rare. Herein, the microstructure of Triton X-100/CnmimNTf2/H2O LLCs formed by using 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ionic liquid (CnmimNTf2, n = 8, 12, 16) as cosurfactant has been determined by polarized light microscopy, small angle X-ray scattering, and 2H NMR technique, and their rheol. and tribol. properties were investigated. These LLCs show good friction-reducing and antiwear performances. The correlation between the microstructure of the LLCs and their lubricating mechanism is established. The increase of the concentration of CnmimNTf2 and the length of alkyl chain in the LLCs can lead to an obvious reduction in friction coefficients and wear volumes, which are attributed to the higher order of amphiphilic mols., the thickness of the amphiphilic bilayer, and the smaller cross-sectional area of the polar head group at the hydrophilic and hydrophobic interfaces. The protective film formed by the phys. adsorption of ionic liquid LLCs on the surface of friction disk pair and the tribochem. reaction has effectively promoted the lubrication effect. The good lubricating property and antiwear capability indicate their promising and potential applications in water lubrication and biol. lubrication. In the experiment, the researchers used many compounds, for example, 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide).

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Mizuno, Cassia S. et al. published their research in Medicinal Chemistry Research in 2009 | CAS: 4887-83-6

7-Methyl-1H-benzo[d]imidazole (cas: 4887-83-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Recommanded Product: 4887-83-6

Design, synthesis, and docking studies of telmisartan analogs for the treatment of metabolic syndrome was written by Mizuno, Cassia S.;Chittiboyina, Amar G.;Patny, Akshay;Kurtz, Theodore W.;Pershadsingh, Harrihar A.;Speth, Robert C.;Karamyan, Vardan T.;Avery, Mitchell A.. And the article was included in Medicinal Chemistry Research in 2009.Recommanded Product: 4887-83-6 This article mentions the following:

In our early studies, telmisartan was found to be a moderate peroxisome proliferator-activated receptor (PPAR) gamma activator in the human PPARγ-GAL-4 cell-based transactivation assay. Thus, novel analogs of telmisartan were designed, synthesized, and evaluated in the AT1 receptor binding assay and PPAR gamma transactivation assay. A total of 11 compounds were designed based on docking in both AT1 receptor model and PPAR gamma active pocket and synthesized. Introduction of an addnl. acidic group at the para position of the distal Ph ring of telmisartan decreased affinity towards AT1 receptor and PPARγ activity. In the present study, the mol. with best results was I, with weak PPARγ activity (8% of maximum PPARγ activation achieved by full agonist rosiglitazone at 10 μM) and good binding affinity (Ki = 650 ± 139 nM) towards the AT1 receptor. Docking of I into AT1 receptor model and PPAR gamma showed very similar interactions with the receptors as AT1 antagonist telmisartan and PPAR gamma agonist rosiglitazone. In the experiment, the researchers used many compounds, for example, 7-Methyl-1H-benzo[d]imidazole (cas: 4887-83-6Recommanded Product: 4887-83-6).

7-Methyl-1H-benzo[d]imidazole (cas: 4887-83-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Recommanded Product: 4887-83-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Rodrigues, Joao V. et al. published their research in Green Chemistry in 2014 | CAS: 79917-89-8

1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Related Products of 79917-89-8

Structural-functional evaluation of ionic liquid libraries for the design of co-solvents in lipase-catalysed reactions was written by Rodrigues, Joao V.;Ruivo, Diana;Rodriguez, Ana;Deive, Francisco J.;Esperanca, Jose M. S. S.;Marrucho, Isabel M.;Gomes, Claudio M.;Rebelo, Luis Paulo N.. And the article was included in Green Chemistry in 2014.Related Products of 79917-89-8 This article mentions the following:

Using ionic liquids as co-solvents may improve reaction media in enzyme-based biotechnol. processes. To establish new conditions, large libraries need to be screened for bio-compatibility and protein stabilization. Using a lipase model, we herein describe a combination of methods leading to an expedited evaluation of 61 different solvent compositions In the experiment, the researchers used many compounds, for example, 1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8Related Products of 79917-89-8).

1-Methyl-3-propylimidazolium Chloride (cas: 79917-89-8) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Related Products of 79917-89-8

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Gandini, Annachiara et al. published their research in Journal of Medicinal Chemistry in 2018 | CAS: 3012-80-4

1-Methyl-1H-benzo[d]imidazole-2-carbaldehyde (cas: 3012-80-4) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.HPLC of Formula: 3012-80-4

Tau-Centric Multitarget Approach for Alzheimer’s Disease: Development of First-in-Class Dual Glycogen Synthase Kinase 3β and Tau-Aggregation Inhibitors was written by Gandini, Annachiara;Bartolini, Manuela;Tedesco, Daniele;Martinez-Gonzalez, Loreto;Roca, Carlos;Campillo, Nuria E.;Zaldivar-Diez, Josefa;Perez, Concepcion;Zuccheri, Giampaolo;Miti, Andrea;Feoli, Alessandra;Castellano, Sabrina;Petralla, Sabrina;Monti, Barbara;Rossi, Martina;Moda, Fabio;Legname, Giuseppe;Martinez, Ana;Bolognesi, Maria Laura. And the article was included in Journal of Medicinal Chemistry in 2018.HPLC of Formula: 3012-80-4 This article mentions the following:

Several findings propose the altered tau protein network as an important target for Alzheimer’s disease (AD). Particularly, two points of pharmacol. intervention can be envisaged: inhibition of phosphorylating tau kinase GSK-3β and tau aggregation process. On the basis of this consideration and on the authors’ interest in multitarget paradigms in AD, the authors report on the discovery of 2,4-thiazolidinedione derivatives endowed with such a profile. 28 and 30 displayed micromolar IC50 values toward GSK-3β, together with the capacity of inhibiting AcPHF6 aggregation of 60% and 80% at 10 μM, resp. In addition, they showed PAMPA-BBB permeability, together with a suitable cellular safety profile. 30 also displayed inhibition of both K18 and full-length tau aggregations. Finally, both compounds were able to improve cell viability in an okadaic acid-induced neurodegeneration cell model. To the best of the authors’ knowledge, 28 and 30 are the first balanced, nontoxic, dual-acting compounds hitting tau cascade at two different hubs. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-benzo[d]imidazole-2-carbaldehyde (cas: 3012-80-4HPLC of Formula: 3012-80-4).

1-Methyl-1H-benzo[d]imidazole-2-carbaldehyde (cas: 3012-80-4) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.HPLC of Formula: 3012-80-4

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Stagel, Kristof et al. published their research in ACS Sustainable Chemistry & Engineering in 2022 | CAS: 404001-48-5

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Halide-Free Continuous Synthesis of Hydrophobic Ionic Liquids was written by Stagel, Kristof;Szpecht, Andrea;Zielinski, Dawid;Smiglak, Marcin;Schnuerch, Michael;Bica-Schroeder, Katharina. And the article was included in ACS Sustainable Chemistry & Engineering in 2022.Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide This article mentions the following:

A novel approach for the halide-free, continuous-flow preparation of hydrophobic ionic liquids (ILs) relying on the bis(trifluoromethanesulfonyl)imide (bistriflimide, NTf2–) anion. The simple yet fast two-step synthetic route, which involved the formation of different alkyl bistriflimides (RNTf2), followed by the quaternization with an amine nucleophile, led to the desired ILs in high yields and excellent purities without any byproduct formation. The variable alkyl chain (R) length and the broad range of the applicable nucleophiles offer considerable flexibility to the synthetic protocol. The quaternization could be performed under solvent-free conditions; moreover, the homogeneous nature of these reactions allowed the application of modern continuous-flow technologies. Given these advantages, the methodol. could afford not just a fast and efficient alternative for the conventional synthesis of such compounds with reduced waste water production but their negligible halide content might provided a significantly broader application range of the IL products, especially for the field of materials science. In the experiment, the researchers used many compounds, for example, 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide).

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Safety of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Ilia, Gheorghe et al. published their research in Journal of the Iranian Chemical Society in 2018 | CAS: 35487-17-3

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.HPLC of Formula: 35487-17-3

Solvent-free synthesis of tris(4-hydroxybutyl acrylate) phosphate in the presence of 1-methylimidazole was written by Ilia, Gheorghe;Macarie, Lavinia;Plesu, Nicoleta;Iliescu, Smaranda;Popa, Adriana. And the article was included in Journal of the Iranian Chemical Society in 2018.HPLC of Formula: 35487-17-3 This article mentions the following:

In this paper, we present the synthesis of tris(4-hydroxybutyl acrylate) phosphate using 1-methylimidazole as acid scavenger for hydrochloric acid byproduct, when an ionic liquid is formed. The synthesis was performed in the absence of any organic solvent. The yield is 83% for ester. The phosphate was characterized by 1H-31P NMR and FTIR. The obtained phosphate is appropriate monomer for UV curing in the presence of photoinitiator. The obtained polymer was characterized by thermal anal. and LOI. The results showed good thermal stability and flame retardancy of UV-cured polymer. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3HPLC of Formula: 35487-17-3).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.HPLC of Formula: 35487-17-3

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Xiao, Linfei et al. published their research in Journal of CO2 Utilization in 2014 | CAS: 35487-17-3

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Formula: C4H7ClN2

Protic ionic liquids: A highly efficient catalyst for synthesis of cyclic carbonate from carbon dioxide and epoxides was written by Xiao, Linfei;Su, Dan;Yue, Chengtao;Wu, Wei. And the article was included in Journal of CO2 Utilization in 2014.Formula: C4H7ClN2 This article mentions the following:

An efficient, inexpensive, easily prepared and sustainable catalytic system of protic ionic liquids was developed for cycloaddition of CO2 and epoxides to produce cyclic carbonates without using any co-catalyst and organic solvent. The effects of the acidity and structure of protic ionic liquid on the catalytic performance were investigated and the various reaction conditions were optimized. Notably, this catalyst was used for five times at least without appreciable loss of catalytic activity and applied for various epoxide for synthesis of corresponding cyclic carbonate in high selectivity and yield. Addnl., a mechanism for the synergistic effects of cation and anion in protic ionic liquids was also proposed. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Formula: C4H7ClN2).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Formula: C4H7ClN2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Hao, Shuai et al. published their research in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices in 2021 | CAS: 915358-85-9

1-Butyl-3-vinyl-1H-imidazol-3-ium hexafluorophosphate(V) (cas: 915358-85-9) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Reference of 915358-85-9

A novel strategy for fabricating highly stretchable and highly conductive photoluminescent ionogels via an in situ self-catalytic cross-linking reaction in ionic liquids was written by Hao, Shuai;Zhang, Jianxin;Yang, Xuemeng;Li, Tianci;Song, Hongzan. And the article was included in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices in 2021.Reference of 915358-85-9 This article mentions the following:

We report a new method to fabricate highly stretchable and highly conductive fluorescent ionogels via self-catalytic crosslinking of poly(ionic liquid (IL))-based copolymers containing epoxy groups in ILs without adding any conventional crosslinkers and chromophores. Here, the ILs serve as a solvent, electrolyte, and catalyst, while the product of the ring-opening reactions acts as crosslinking junctions. The results reveal that these systems are typical autocatalytic systems and that the IL anion type significantly influences the curing reaction kinetics. These ionogels exhibit excellent stretchability (>1200%), high ionic conductivity (>1 mS cm-1), and good temperature tolerance (-40 to 200°C). Surprisingly, the special crosslinking structures make the ionogels show typical aggregation-induced emission behavior and possess tunable photoluminescence properties. Moreover, ionogel-based strain sensors exhibit fast response speed, excellent temperature tolerance and stability, and can monitor various human motions. Therefore, our study provides a facile method to utilize several distinct properties of ILs and PILs for designing multifunctional ionogels that serve as flexible conductive and fluorescent materials. In the experiment, the researchers used many compounds, for example, 1-Butyl-3-vinyl-1H-imidazol-3-ium hexafluorophosphate(V) (cas: 915358-85-9Reference of 915358-85-9).

1-Butyl-3-vinyl-1H-imidazol-3-ium hexafluorophosphate(V) (cas: 915358-85-9) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Reference of 915358-85-9

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem