Chandra, Tilak published the artcileRegio- and Stereoselective Glycosylation: Synthesis of 5-Halo-Imidazole α-Ribonucleosides, HPLC of Formula: 30086-17-0, the main research area is crystal mol structure haloimidazole nucleoside synthesis stereoselective regioselective glycosylation; stereoselective regioselective glycosylation synthesis halogen imidazole nucleoside synthon cobalamin.
We describe the synthesis of novel 5-halo-imidazole ribonucleosides, e.g. I, as precursors of modified cobalamins. A regio- and stereoselective glycosylation of protected ribose with silylated 4(5)-halo-imidazoles produces 5-halo-imidazole ribonucleosides predominantly in the α-configuration (60-75%) without any 4-substituted imidazole ribonucleoside. The structure of the 5-fluoroimidazole ribonucleoside was confirmed by X-ray crystallog. and 2D NMR spectroscopy.
Journal of Organic Chemistry published new progress about Corrinoids Role: SPN (Synthetic Preparation), PREP (Preparation). 30086-17-0 belongs to class imidazoles-derivatives, name is 5-Fluoro-1H-imidazole, and the molecular formula is C3H3FN2, HPLC of Formula: 30086-17-0.
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem