Imidazole-containing bispidine ligands: synthesis, structure and Cu(II) complexation was written by Walther, Martin;Matterna, Madlen;Juran, Stefanie;Faehnemann, Silke;Stephan, Holger;Kraus, Werner;Emmerling, Franziska. And the article was included in Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences in 2011.Recommanded Product: (1H-Imidazol-2-yl)methanamine dihydrochloride This article mentions the following:
The preparation and characterization of tris-pyridyl bispidine (3,7-diazabicyclo[3.3.1]nonane) derivatives with benzimidazole and imidazole donor groups at the N-3 position of the bispidine skeleton and their copper(II) complexes are reported. The impact of the hetaryl substituents on the configurational isomerism of piperidones and their corresponding bispidones was studied by NMR spectroscopy, revealing the exclusive appearance in the enol form for the piperidones in solution and the trans-configuration regarding the two pyridyl substituents, as well as the sole formation of the unsym. exo-endo isomers for the corresponding bispidones. Thus, the bispidones are preorganized ligands for building pentacoordinated complexes, confirmed by the preparation and characterization of the corresponding Cu(II) complexes. Of the di-pyridyl piperidones with benzimidazole and imidazole substituents, and of the Cu(II) complex of the benzimidazole-containing bispidone, crystals have become available for the anal. by x-ray diffraction, showing that the piperidones form the enol tautomers also in the solid state. In the experiment, the researchers used many compounds, for example, (1H-Imidazol-2-yl)methanamine dihydrochloride (cas: 22600-77-7Recommanded Product: (1H-Imidazol-2-yl)methanamine dihydrochloride).
(1H-Imidazol-2-yl)methanamine dihydrochloride (cas: 22600-77-7) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Recommanded Product: (1H-Imidazol-2-yl)methanamine dihydrochloride
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem