614-97-1, A common compound: 614-97-1, name is 5-Methyl-1H-benzo[d]imidazole, belongs to imidazoles-derivatives compound, it can change the direction of chemical reaction, and react with certain compounds to generate new functional products. A new synthetic method of this compound is introduced below.
General procedure: In a typical reaction procedure, benzimidazole (1mmol), different derivatives of ammonia (1mmol), 0.5 mol% [Ru(bpy)3]Cl2 were taken in a single necked round bottom flask. The reaction mixture was stirred at room temperature under blue light. The completion of the reaction (indicated by disappearance of the starting material and formation of new product, observed by TLC (30:70%) ethyl acetate and hexane. After the product formation 15 ml ethyl acetate and 10 ml water were added. The organic reactants and product were taken out with ethyl acetate and [Ru(bpy)3]Cl2 were dissolved and taken out with water.
In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 5-Methyl-1H-benzo[d]imidazole, other downstream synthetic routes, hurry up and to see.
Reference:
Article; Siddiqui; Ibad, Farah; Ibad, Afshan; Abdul Waseem, Malik; Watal, Geeta; Tetrahedron Letters; vol. 57; 1; (2016); p. 5 – 10;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem